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And with that, it is my pleasure to welcome everyone to today's internet seminar. You should be joining us for part one of a two-part webinar series on the framework for investigating asbestos contaminated circle sites.

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My name is Jean Balance coming to you from EPA's Technology Innovation and Field Services Division, where I will be serving as a technical moderator in the background for today's broadcast.

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And we're joined by a series of technical experts who will be helping to answer questions and facilitate conversations during our broadcast.

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But before I officially launch into the presentation content and then we begin our Q&A breaks.

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What I'd like to do is walk through a series of housekeeping items to make sure that everyone understands how to participate in today's broadcast.

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The first important reminder is that there is a unique seminar homepage for our session today.

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That homepage is found at the URL shown in red at the top of the slide. You can access it by the QR code that I have in the lower right on the screen. It's also the same website that you were directed to when signing up. It's the same website that I sent you to.

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Via my confirmation and reminder emails. And it's the same website that I'll send you to if you're looking for copies of the presentation materials, the framework document, and a whole slew of resources that will be highlighted in today's broadcast.

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All right, today we're going to be hosting today's session live through Zoom. You should be able to participate using the free Zoom application or through a web browser of your choice.

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The meeting chat has been disabled, meaning that you can't send messages into the chat, but I, as the moderator may periodically send links or references to you through that chat.

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We will pause throughout our session today and take questions from the live audience so that our experts can respond to them. But there is no need to wait for those designated breaks. In fact, I encourage you to type them up as soon as they occur to you.

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We are recording today's session and the entire series will be archived on the Kluwen website. You'll automatically get an email when the archive is available for on-demand replay. And please stick with me until the very end because I'm going to walk through some important reminders including how you can receive a certificate of participation based on today's session. So visually, I know many of you are already familiar with Zoom, but I've had two people ask me to do this already. So just quickly, if this is brand new to you.

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The controls typically appear on the bottom of Zoom. So audio controls will appear in the lower left.

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With the presentation materials occupying the main portion of your screen. We'll periodically have speaker videos off to the side, but you have additional controls in the upper right and upper center.

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Now, I think that's the end of the technical reminders that I have. So with that, I'm going to ask the audience to go ahead and send in a quick message to me in the Q&A if you are ready to get started.

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As I'm waiting for some of those messages to come in, I'm going to go ahead and start teeing up the presentation materials so that we can officially launch So looking at all of those messages that you are ready to go with today's part one of the framework for investigating asbestos Contaminated circulates, let me pull up the presentation content and get started with our broadcast today.

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This training was developed by the Asbestos Technical Review Workgroup. Or TRW.

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It aligns with the recent update to the framework for Investigating Asbestos Contaminated comprehensive environmental response.

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Compensation and Liability Act. Or circla sites, which was also developed by the Asbestos TRW.

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The asbestos is comprised of members from regional offices. Office of Land and Emergency Management.

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Or OLIM, Office of Research and Development. Or ORD, and the Agency for Toxic Substance Disease Registry or ATSDR.

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Their mission is to provide technical support for questions concerning the assessment, removal.

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Or remediation of asbestos contamination at circler sites.

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They can answer any questions regarding this presentation or other asbestos related questions.

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For Superfund site assessments. The hotline email address is asbestoshelp at epa.gov.

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Or you can contact your regional or office representative. Contact information for the asbestos TRW co-chairs can be found using this link or QR code.

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Which directs you to the asbestos TRW Technical Assistance website.

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An updated framework for investigating asbestos contaminated surplusites was released in 2021.

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This document updated a 2008 version. The QR code and the hyperlink on this slide will take you to the updated document.

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It provides Superfund regional remedial and removal project managers. On-scene coordinators.

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Site risk assessors, and other site decision makers with information to assist in asbestos risk evaluation at Superfund sites.

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It recommends a site-specific approach to using air measurements of asbestos fibers released during soil and dust disturbing activities.

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This flowchart is a condensed outline of the investigation process described in the updated framework.

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The investigation process outlined in the updated framework follows the traditional remedial investigation or RI process.

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With some deviations due to the unique properties of asbestos. This is a flexible process which allows users to take response action at any point.

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We will circle back to this process near the end of this training.

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Where we will go through each of the steps within this flowchart one by one.

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Before that, we will review the definition of asbestos. An asbestos sampling, and analytical recommendations.

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Asbestos risk assessment recommendations are provided at the end of this presentation.

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What asbestos is depends on the perspective of who is describing it.

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Geologists will describe asbestos based on its mineral type and morphology.

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Commercially, asbestos is used in manufacturing for its beneficial properties. For example, thermal and chemical resistance tensile strength and durability.

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And produces asbestos containing material or ACM.

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The amount of asbestos in a product determines if the material is considered ACM.

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A laboratory analyst will describe asbestos based on what they see and sample under a microscope. For example, fiber dimensions and morphology characteristics.

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Different agencies and organizations that regulate asbestos We'll describe the properties or characteristics of the type of asbestos that they regulate.

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Depending on your audience, you may need to describe asbestos to ensure you are talking about the same thing.

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In geological terms, asbestos is a silicate. Silicates are minerals containing silicon and oxygen In a tetrahedron-shaped ionic group.

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Abbreviated as SIO4. They are also classified by distinct crystalline structures and different cations, such as calcium.

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Ferrous iron, aluminum. Magnesium, etc.

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In mineralogy, the characteristic external shape of an individual crystal or aggregate of crystals is called the crystal habit.

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The habit of formation for asbestos fibers refers to the unusual crystallization habit of a mineral when crystals are thin, hair-like fibers.

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This characteristic habit is called asbesta form.

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There are over 60 known varieties of asbestos. They are usually classified into one of two mineral groups.

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Serpentine or amphibole? Serpentine has a wavy appearance.

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Whereas amphibles appear as straight needle-like fibers. Chrysotile is the only type of asbestos that is serpentine.

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Most asbestos that is used in man-made products is chrysotile. There are several types of amphibole asbestos.

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Including amycite, crocidolite. Anthopholite, actinolite.

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And tremolite.

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Chrysotile is known as white asbestos. It is the most common type of asbestos used around the world.

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With some countries still permitting controlled use. Approximately 93% of asbestos containing materials or ACM, is made up of chrysotile.

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Examples of chrysotile containing ACM include cement pipe and sheets. Roofing, thermal and electrical insulation.

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Flooring, gaskets. Brake pads and shoes, coating and compounds and millboard.

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Crocytolite is known as blue asbestos. It is rarely used in commercial products it is less heat resistant than other asbestos fibers.

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However, it can be found in steam engines. Spray on coatings.

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Pipe insulations, plastics. And submit products.

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Amycite is known as brown asbestos. It is most frequently used in cement sheets and high temperature high heat capacity pipe insulation.

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As it has a high level of heat resistance.

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Anthophyllite is one of the rarest types of asbestos. Its coloring can vary from gray to green.

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Brown and beige. It does not have a long history of commercial use.

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But can be found in cement, insulation. Roofing material, and rubber.

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Due to being relatively inert and stable in the presence of heat or acid.

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Trimolite can be brown, white. Green, gray, or transparent.

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Actinolite can be pale to dark green. Yellowish green and black.

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And appears to be white or transparent. Both are rarely included in commercial products.

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They're usually found in trace amounts when other minerals are being mined.

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But high levels have been identified in vermiculite ore. Mining vermiculite ore with tremolite And actinolite has led to widespread exposures and adverse health effects, as seen at the Libby mine in Montana.

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Libby amphibole asbestos or LAA is comprised of several amphibole minerals which were identified in the Rainy Creek Complex at the Libby, Montana vermiculite mine.

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The amphibole mixture that makes up LAA includes wind chite.

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Richterite, tribalite. Magnesio Rebecite.

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Magnesio arvetzanite. And edonite.

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Epa has developed separate toxological values for assessing risk posed by general asbestos and LAA.

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This is discussed later in the risk assessment recommendations section.

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The general term asbestos was applied to minerals with long flexible fibers.

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High tensile strength. Durability and heat resistance.

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Amphibles are also known for their acid and alkaline resistance. These properties make asbestos appealing for commercial use.

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Commercially, asbestos containing material or ACM, is any material containing greater than 1% asbestos.

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If any of the minerals we just reviewed in the geological perspective section.

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Are chemically altered, such as adding a binder to make a product.

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Then that product is considered ACM. Common types of ACM encountered at surplus sites include pipe insulation.

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Shingles and cement.

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Asbestos is analyzed by microscopy. The analytical method used will determine counting rules for asbestos analysis.

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Counting rules are used by microscopists During asbestos analysis.

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And will be discussed in more detail later in this training.

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For some analytical methods, a microscopist will identify what is seen under a microscope As asbestos by structure type, such as fibers and bundles.

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We'll record the length and width of each structure And we'll also identify the mineral type of each structure.

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The analytical method and or the defined counting rules will dictate what structures are considered asbestos.

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Different structure types, sizes, and mineral types may be excluded. The images on this slide are photographs of asbestos taken through a microscope.

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As you can see in these images. Multiple structures can be seen within the field of view of a microscope.

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During asbestos analysis. There could be mixtures of different particle sizes, structure types, and mineral types.

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The image on the left shows different structure types of tremolite, such as fibers and bundles.

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The image on the right shows an amyte fiber bundle. The brighter straight structure mixed with the curved chrysotile structures.

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Asbestos is a listed circular hazardous substance. Under 40 CFR, Part 302. Asbestos is also addressed by other statutes and regulations.

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Some examples include the Asbestos Hazard Emergency Response Act. Or ahira, which is under the Toxic Substances Control Act.

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Known as TSCA, the asbestos National Emission Standards for Hazardous Air Pollutants Or Nishap under the Clean Air Act.

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Osha General Industry and Construction Standards. In the asbestos maximum contaminant level, or MCL, Under the Clean Water Act.

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Note that different laws have different perspectives or definitions of asbestos.

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When discussing asbestos and the framework. The asbestos TRW states that asbestos is the generic name used for a group of naturally occurring mineral silicate fibers.

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Of the serpentine and amphibole series. Displaying similar physical characteristics Although differing in composition.

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It is a group of highly fibrous silicate minerals that readily separate into long thin strong fibers that have sufficient flexibility to be woven.

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Are heat resistant and chemically inert are electrical insulators and therefore are suitable for uses where incombustible non-conducting or chemically resistant materials are required.

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Description is intended to cover all mineral forms of asbestos that may be subject to circular authority and are associated with health effects in humans.

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Additionally, the framework may be useful For site assessment of other elongate mineral particles.

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Where health effects similar to asbestos such as mesothelioma have been indicated.

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Area night is one example of an elongate mineral particle that has been found on Superfund sites.

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The asbestos types that were just discussed on previous slides are typically magnesium silicates.

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Where Zeolites, like Arianite. Are aluminum silicates.

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Some properties of arionite, such as its chain-like structure. Are similar to the properties of asbestos.

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However, other properties, such as refractive index. Much different. Area night forms brittle, wool-like fibrous masses in the hollows of rock formations.

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For more information on Area Night or other elongate mineral particles.

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Please consult the framework and or the TRW Asbestos Committee.

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All right, ladies and gentlemen, we're going to take our first Q&A break at this time.

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And I'm going to ask some of my panelists to come on camera and I'll remind the live audience, if you have a question or comment.

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Go ahead and click the Q&A button at the bottom of your screen and you can type your message on in. I'm going to start reading through some of the questions that have already come into the Q&A.

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And this very first question, I'm going to take it and I might direct it at Joey because it gets into the structure of the course and what we may cover during this series.

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Is if we're going to discuss risk associated with exposure to asbestos in this class.

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Yeah, absolutely. We will be getting to that a little bit today and more on risk assessment tomorrow. So absolutely.

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Thank you. And so my next question Is asbestos used commercially in the US anymore? I thought it was banned decades ago.

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I can start this off. I know the main industry is the chloral alkali industry.

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Sure.

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So a group of plants for operating facilities Not many left, but around the US that they are the major consumer or user of asbestos. And that's mainly for gasket and the properties that are used.

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The high heat situations for chloralkali plants. But as far as commercially, if anyone else wants to jump in and talk a little bit about asbestos bands or That kind of stuff, feel free.

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Yeah, sure. It hasn't been fully banned in the United States just yet.

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And while we're still talking about it is from its use in building materials that have been around for many years. I think the thought was that it would have been fully removed from those buildings at this point, but that was not the case.

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So we're still dealing with it. At EPA from buildings that are improperly torn down and spread asbestos around.

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And in the case of Libby, we've learned that damaging are moving naturally occurring asbestos.

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In its geologic setting can also be harmful.

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So that's, I guess, sort of the context of why we're still talking about it, even though it's been largely disused in building materials.

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Okay.

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And to add to what Tim has said. Vermiculite or from vermic or from the Libby mine has been or was used extensively for home insulation.

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So there are a number of homes throughout the United States.

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That still have vermiculite attic insulation.

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And if that is encountered. One should contact a qualified asbestos removal firm.

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To address the issue. Of attic insulation.

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Okay. Anyone else want to chime in?

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Okay, I'm going to move on to our next question. And this one is asking because we talked about all the different types of asbestos in the presentation so far.

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So some of the participants are wondering if cleanup varies by the type of asbestos, or is it pretty much the same approach regardless of which form you're dealing with?

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And I may pick, there we go, Joey. It's like, I'll start with you.

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I'm not shy. And I say, I'll start it off. There are commonalities in asbestos cleanups.

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Things like our work practices, our decon techniques. Even our disposal practices.

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Are going to be very, very similar. No matter what the type is. I'll let others join in here, but I believe Sometimes the characterization, so things like sampling and figuring out just where your area of concern is going to maybe depend on the type of asbestos.

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Anyone want to add to differences in cleanup approaches based on asbestos type.

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Well, I think you've encapsulated it there. So thank you joke Appreciate it.

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Yeah. I'm sure there are nuances as well as, and we'll get into it, especially when it comes to analysis as well.

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Depending on what type of asbestos you have. So we will talk about that part as well later.

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Excellent. We have one more question in the queue that I'll take now. And this is in the form of who should I call Does the state get to call EPA or someone else? Who do I call if I think I've encountered asbestos at a site?

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Yeah, I guess that depends on the state that you're in and the asbestos that you're encountering.

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Most states have delegated programs to enforce asbestos regulations like in buildings in particular So in those cases, those states would be your first point of contact.

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If you're at a Superfund site or something like that where the damage has been done and things are spread around or you're encountering naturally occurring asbestos.

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Possibly EPA would be your your line of… contact your first point of contact but in general You know, the states have that.

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Enforcement authority to go after folks.

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In the Superfund program, things are a little bit different in the types of asbestos that we deal with, but I'd say generally speaking, the states Joey, do you have… When would OSCs be called?

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As a first point of contact.

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Yeah, we need to have a release. Of a hazardous substance, which asbestos is. That was one of the slides into the environment, right? So we can't go after stuff that is part of a building structure, stuff that is Not friable. We'll talk about the definition of friable versus friable.

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But just getting back to this general question, if you are stuck You're not getting an answer from a state or maybe from a local counterpart.

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That's what we are here for, the TRW. You can always reach out and email the asbestos TR&W, we can do a little digging or maybe reach to some of our contacts, whether it's on a state level, local level.

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Okay, and then just a quick clarification. So Joey, if a building is being demolished.

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And they're saying it's release or mobilize that asbestos. It is no longer contained in a structure.

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Is that when EPA could or an OSC could be brought on board?

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Yeah. They can be notified. I would probably call the National Response Center, which is the 800 number to report a release.

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You're going to get likely a more on the ground response. I'm not going to say quicker but If you reach to a state program. So if you just look up your state's environmental program.

00:21:57.000 --> 00:22:11.000
And see, you know, I'm sitting here in region three, so I know Pennsylvania's got a a page right for a page for their asbestos programs and for the release and that kind of stuff and as well as enforcement.

00:22:11.000 --> 00:22:24.000
Osc is an on-scene coordinator, so we're the emergency responders, Colin and i that are on this call are both OSCs for quicker time critical responses.

00:22:24.000 --> 00:22:37.000
All right. Well, at this time, I think we have cleared through the question queues. I think we'll carry on with the presentation. But I want to thank our panelists. They will stay with us. We're going to go through another module here and pause again for a Q&A break.

00:22:37.000 --> 00:22:47.000
I will encourage the audience to continue to submit your questions and comments. So if there's a term, an acronym, a link, a reference, anything that you have a question about, feel free to type that into the Q&A at any time.

00:22:47.000 --> 00:22:55.000
And we'll pause again here in just a moment for another Q&A break.

00:22:55.000 --> 00:23:01.000
The asbestos framework emphasizes an empirical approach to site investigation and characterization.

00:23:01.000 --> 00:23:13.000
Specifically, a combination of samples from media such as air and soil, are recommended to characterize exposures for risk assessment and nature and extent of the contamination.

00:23:13.000 --> 00:23:23.000
The framework provides recommendations for sampling asbestos in soil. Settled dust and air.

00:23:23.000 --> 00:23:34.000
The framework recommends incremental sampling methodology. Or ISM to collect soil samples that are as representative of the sampled areas as possible.

00:23:34.000 --> 00:23:45.000
Because of the inherent heterogeneity of asbestos in soil. Collecting 30 to 100 increments per composite is recommended by the asbestos TRW.

00:23:45.000 --> 00:23:56.000
More increments would provide a more reliable estimate. The potential for subsurface presence Upward migration or future land uses.

00:23:56.000 --> 00:24:05.000
Involving soil excavation. Determines if subsurface asbestos should also be considered in addition to surface samples.

00:24:05.000 --> 00:24:13.000
Careful consideration should also be given to whether sample processing steps should be conducted in the field or in the lab.

00:24:13.000 --> 00:24:19.000
Rigorous and well-considered sample processing is an integral part of ISM.

00:24:19.000 --> 00:24:25.000
The asbestos content of soil is usually low compared to bulk asbestos containing materials.

00:24:25.000 --> 00:24:33.000
So the fraction of particles that are asbestos is small An accurate quantification is very difficult.

00:24:33.000 --> 00:24:40.000
Thus, soil results should generally be interpreted semi-quantitatively. During initial phases of a site assessment.

00:24:40.000 --> 00:24:48.000
And cannot therefore be used for risk assessment. Air sample results are required for risk assessment.

00:24:48.000 --> 00:24:58.000
These and other considerations for soil sampling are discussed in more detail In the next section, starting with slide 34.

00:24:58.000 --> 00:25:01.000
So our results do allow for initial findings that a release has occurred.

00:25:01.000 --> 00:25:08.000
And may help to focus future sampling actions.

00:25:08.000 --> 00:25:14.000
Ism is a composite sampling and processing protocol. That reduces data variability.

00:25:14.000 --> 00:25:20.000
And provides a reasonably unbiased estimate of contaminant concentrations in soil.

00:25:20.000 --> 00:25:28.000
The ISM process includes collecting 30 to 100 increments that are then combined, processed.

00:25:28.000 --> 00:25:40.000
And subsampled according to specific protocols. The Interstate Technology and Regulatory Council Where ITRC provides ISM guidance at the website listed on this slide.

00:25:40.000 --> 00:25:47.000
It can also be accessed using this QR code.

00:25:47.000 --> 00:25:56.000
Dust samples may be collected on solid non-porous surfaces. To identify areas where asbestos is present or absent.

00:25:56.000 --> 00:26:05.000
Currently, there is insufficient information to correlate asbestos content in dust with human exposure to be used in risk assessments at circler sites.

00:26:05.000 --> 00:26:10.000
However, dust information may be used to support risk management actions.

00:26:10.000 --> 00:26:16.000
When exterior, high-level sources are present. That result in high indoor dust levels.

00:26:16.000 --> 00:26:24.000
As with soil sampling, air sample results are required for risk assessment, where asbestos is suspected in indoor dust.

00:26:24.000 --> 00:26:30.000
Two sample collection methods are available for Dust. Micro vacuum and wipe sampling.

00:26:30.000 --> 00:26:44.000
The microvacuum approach, shown on this slide. Is the most commonly used to support indoor investigations And, in general, is the recommended method for sampling dust in indoor environments for asbestos.

00:26:44.000 --> 00:26:49.000
A low suction vacuum captures dust and fibers on a filter cassette.

00:26:49.000 --> 00:26:58.000
Astm D5755 is a standard test method for microvacuum sampling An analysis of asbestos and dust.

00:26:58.000 --> 00:27:07.000
It provides a fiber loading per surface area in units of structures per square centimeter.

00:27:07.000 --> 00:27:14.000
Wipe sampling is an alternative method for dust that may be considered on a site-specific basis.

00:27:14.000 --> 00:27:28.000
Astm D6480-19 is the standard test method or wipe sampling of surfaces, an analysis of asbestos, structures by transmission electron microscopy.

00:27:28.000 --> 00:27:32.000
For this method, a known area of a surface is wiped with a cloth material.

00:27:32.000 --> 00:27:45.000
To collect a sample. Dust results from both microvacuum and wipe sampling are typically compared to a screening level of 5,000 total structures per square centimeter.

00:27:45.000 --> 00:27:54.000
This screening benchmark was used at the World Trade Center and Libby, Montana sites.

00:27:54.000 --> 00:28:01.000
Air sampling is used for regulatory compliance. Environmental condition assessment, and human exposure assessment.

00:28:01.000 --> 00:28:06.000
Air sampling should be performed in the breathing zone if used for risk evaluation.

00:28:06.000 --> 00:28:13.000
Activity-based sampling, or ABS, is the recommended sampling method for human health risk assessment.

00:28:13.000 --> 00:28:20.000
Abs should be performed while conducting a dust generating activity Typical for the site, like raking.

00:28:20.000 --> 00:28:30.000
Jogging, and gardening. Passive air samples may not reflect potential exposure of activities that disturb soil.

00:28:30.000 --> 00:28:35.000
Additional information is contained in Appendix E of the 2021 Framework.

00:28:35.000 --> 00:28:47.000
This is an ERT Helpful Hint. For ABS document, which can be accessed either in the framework or at the link on this slide.

00:28:47.000 --> 00:28:55.000
Why activity-based sampling? As shown in this figure, fiber is located in indoor and outdoor environments.

00:28:55.000 --> 00:29:00.000
Such as those entrained in a carpet indoors are mixed with soils outdoors.

00:29:00.000 --> 00:29:09.000
Can be mobilized and released into air when disturbed. We are interested in capturing the fibers in the breathing zone for human health risk assessment.

00:29:09.000 --> 00:29:15.000
Because air concentrations cannot currently be calculated using soil and dust concentrations.

00:29:15.000 --> 00:29:31.000
Air sampling is required for risk assessment The resuspension of particulates, including fibers from human activity during ABS, produces a personal cloud that can be sampled as breathing zone air for risk evaluation.

00:29:31.000 --> 00:29:36.000
Site-specific factors such as nature and the type of asbestos material.

00:29:36.000 --> 00:29:47.000
Soil properties, weather, and the level and type of disturbance all impact what can get into the air.

00:29:47.000 --> 00:30:13.000
In addition, asbestos is not uniformly distributed in soil. Soil concentrations less than 1% have been demonstrated to represent significant risk when disturbed. Using 1% as a screening benchmark is not health As you can see in these photos, soil can hide a lot of asbestos.

00:30:13.000 --> 00:30:20.000
Activity-based outdoor sampling uses an activity that produces a high-end soil disturbance.

00:30:20.000 --> 00:30:36.000
The raking scenario is the recommended high-end outdoor activity. The image shows a sampler raking While wearing the appropriate PPE, For a specified time over an area of concern.

00:30:36.000 --> 00:30:43.000
An area of concern could be broken out into grids. Or decision units depending on the size.

00:30:43.000 --> 00:30:49.000
Personal air samples from the breathing zone are collected during the activity.

00:30:49.000 --> 00:30:55.000
In this photo, the backpack the sampler is wearing contains the sampling equipment.

00:30:55.000 --> 00:31:02.000
Once analyzed, the sample provides a site-specific measure of fiber release from soil.

00:31:02.000 --> 00:31:12.000
The concentration of asbestos in the breathing zone that results from the activity In this case, raking.

00:31:12.000 --> 00:31:20.000
Abs scenarios should be typical high-end activities Representative of current or future use at the site.

00:31:20.000 --> 00:31:29.000
The generic ABS scenario is raking with a leaf rake. Other examples of ABS scenarios include rototilling.

00:31:29.000 --> 00:31:34.000
A child playing in the dirt. Lawn mowing, bicycling, jogging.

00:31:34.000 --> 00:31:39.000
Playing soccer, driving. Atv writing, digging.

00:31:39.000 --> 00:31:47.000
Weed whacking, walking with a stroller. Playing basketball, hiking, motorcycling, and gardening.

00:31:47.000 --> 00:31:54.000
The following slides will show photos of different ABS scenarios that have been used in the past.

00:31:54.000 --> 00:32:02.000
Work with a risk assessor to select an ABS activity that represents high-end exposure for your site.

00:32:02.000 --> 00:32:07.000
For additional information on ABS, Refer to Appendix E of the EPA framework.

00:32:07.000 --> 00:32:19.000
Which is ERT's Helpful Hints for ABS Sampling. An EPA ERT SOP 2084.

00:32:19.000 --> 00:32:26.000
Working slash occupational scenarios include raking.

00:32:26.000 --> 00:32:31.000
Digging.

00:32:31.000 --> 00:32:36.000
Lawn mowing.

00:32:36.000 --> 00:32:41.000
Weed whacking.

00:32:41.000 --> 00:32:47.000
And rototilling.

00:32:47.000 --> 00:32:52.000
Recreational scenarios include walking with a stroller.

00:32:52.000 --> 00:33:02.000
Note that the breathing zone for this scenario is both inside of the stroller and close to the face of the adult pushing the stroller.

00:33:02.000 --> 00:33:16.000
Atv writing, note that it is important to have two vehicles participate in this activity As the dust and particulate exposure is greater for the trailing vehicle.

00:33:16.000 --> 00:33:26.000
Bike riding. Again, multiple bikes are needed to adequately assess exposure to the trailing bikes.

00:33:26.000 --> 00:33:40.000
Hiking, note that two air sampling cassettes or sampling points are placed on one sampler to measure the breathing zone for both an adult and child hiker

00:33:40.000 --> 00:33:46.000
Playing soccer.

00:33:46.000 --> 00:33:57.000
Driving on an unpaved road Again, multiple vehicles should be used to assess exposure for the trailing vehicle.

00:33:57.000 --> 00:34:08.000
Child playing in the dirt with a shovel and bucket. Note that the error sampling cassette or sampling point is lower or closer to the bucket than the adult breathing zone.

00:34:08.000 --> 00:34:14.000
As this scenario is meant to be representative of a child.

00:34:14.000 --> 00:34:19.000
Activity-based indoor sampling scenarios may include the use of fans.

00:34:19.000 --> 00:34:27.000
Leaf blowers, and brooms. Air samples are collected from the breathing zone as well as perimeter air samples.

00:34:27.000 --> 00:34:36.000
Sample results provide a quantitative concentration of fibers in air resulting from dust disturbance.

00:34:36.000 --> 00:34:50.000
Some key points about ABS and air sampling include, one. Measurements made directly from the breathing zone are the most valuable Two, ABS is the most reliable estimate of exposure.

00:34:50.000 --> 00:34:59.000
Three, dust measurements and or solid media data For example, soil or soil ACM, etc.

00:34:59.000 --> 00:35:03.000
Cannot currently be converted to air concentration data for risk assessment.

00:35:03.000 --> 00:35:08.000
Dust sample results may be used to support risk management decisions.

00:35:08.000 --> 00:35:22.000
See slide 24. And four, measurements from stationary air monitors may not provide reliable estimates of human inhalation exposure.

00:35:22.000 --> 00:35:34.000
The link and QR code on this slide are for a video that covers an overview and considerations for ABS sampling.

00:35:34.000 --> 00:35:41.000
All right. At this time, I'm going to go ahead and pull up a video and play that for everyone.

00:35:41.000 --> 00:35:44.000
So bear with me while I call that up and move it over to the screen.

00:35:44.000 --> 00:35:52.000
If… If you encounter any technical difficulties in watching the video here.

00:35:52.000 --> 00:36:11.000
Through Zoom, we do recognize that it sometimes periodically doesn't play back with the best quality. I'm going to place a link to this video directly as well in the chat so you can play it back locally.

00:36:11.000 --> 00:36:34.000
The 2021 Framework for Investigating Asbestos Contaminated Circlisites provides remedial and removal managers, remedial project managers, on-scene coordinators, site assessors, and other decision makers with information to assist in the evaluation of asbestos risks at Circlisites. This video guides site managers

00:36:34.000 --> 00:36:43.000
Through the process of collecting samples, such as soil, dust, and air, and describes activity-based sampling procedures, or ABS.

00:36:43.000 --> 00:36:52.000
Including area selection. Grid market, perimeter and background sampling, various ABS scenarios, and considerations for site cleanup.

00:36:52.000 --> 00:37:15.000
Performing ABS is included in steps four and five. Of the asbestos decision framework for outdoor and indoor environments. As included in the 2021 Framework for investigating asbestos Contaminated circle sites.

00:37:15.000 --> 00:37:27.000
Keep the area selected for ABS sampling relatively level and free of any standing water or excess trip hazards.

00:37:27.000 --> 00:37:38.000
Areas with thick vegetation should be trimmed. Remove plastic sheeting from grids and soil and allow sufficient time for drying.

00:37:38.000 --> 00:38:02.000
Clearly define the grid area with high visibility markings. Mark sampling activities including grid corners with a GPS receiver coupled with an application such as field maps.

00:38:02.000 --> 00:38:16.000
Established decision units for the site using a GIS software. Once decision units are established, determine the sample design to be implemented. Typical sample designs include composite sampling.

00:38:16.000 --> 00:38:25.000
Discrete sampling. And the recommended method of the incremental sampling methodology.

00:38:25.000 --> 00:38:47.000
Following the sample design selected, use a scoop or trowel To collect the required number of surface samples. Label each homogenized sample for delivery to the lab.

00:38:47.000 --> 00:39:00.000
The 2021 framework provides additional details related to soil sample analysis. A common method employed includes polarized light microscopy, or PLM.

00:39:00.000 --> 00:39:17.000
However, sampling at multiple sites has shown that even when soils are non-detected by PLM, with a reporting limit of less than 0.25% concentrations of asbestos in the air via ABS may result in unacceptable health risks.

00:39:17.000 --> 00:39:26.000
Therefore, although soil samples exceeding 0.25% asbestos can be used to make a determination to clean up a grid.

00:39:26.000 --> 00:39:34.000
Abs is recommended to rule out risk concerns in grids with trace or even non-detect results in soil.

00:39:34.000 --> 00:40:04.000
To ensure risk thresholds are not exceeded when the material is disturbed. The following table shows an instance where soil data analyzed by PLM indicated non-detect and trace results. While ABS employed in the same sampling grids identified more substantial results.

00:40:05.000 --> 00:40:10.000
Perform ABS in as dry as possible conditions for the worst case scenario.

00:40:10.000 --> 00:40:16.000
Collect soil moisture readings from at least 10 locations within the ABS grid.

00:40:16.000 --> 00:40:32.000
A soil moisture reading of 10% or less is recommended to capture optimum contaminant release.

00:40:32.000 --> 00:40:48.000
Interior air sampling for asbestos requires a tripod. Sample pump, tubing, a calibration unit, and appropriate sample media For the analytical method, select it.

00:40:48.000 --> 00:40:53.000
Calibrate the sample pumps to the required flow rate for the analytical method selected.

00:40:53.000 --> 00:41:13.000
And place sample media within the breathing zone. Interior samples are typically collected in a representative functional space from within the structure.

00:41:13.000 --> 00:41:26.000
Collect indoor dust samples on solid, non-porous surfaces to determine where asbestos may be present. The preferred method for dust sample collection includes the microvacuum method.

00:41:26.000 --> 00:41:32.000
This method typically requires a sample template, typically 10 centimeters by 10 centimeters.

00:41:32.000 --> 00:41:43.000
A calibrated personal sampling pump and sampling cassettes with a one to two inch piece of tubing are cut to a 45 degree angle to allow micro vacuum sampling.

00:41:43.000 --> 00:41:51.000
Vacuum the area within the template using a consistent back and forth motion, covering the template area for the required duration.

00:41:51.000 --> 00:42:00.000
Dust sampling can also be conducted with the wipe method. This method is similar to the microvac method but requires no specialized equipment. In this method.

00:42:00.000 --> 00:42:09.000
Wipe the template using the laboratory supplied wipe that is folded to allow for a clean section for each direction wiped in the template.

00:42:09.000 --> 00:42:17.000
Note that dust sampling is similar to soil sampling, in that the type of data obtained is not considered suitable for risk assessment.

00:42:17.000 --> 00:42:32.000
To quantitatively evaluate risk. Indoor air samples are necessary.

00:42:32.000 --> 00:42:50.000
Determine data quality objectives and the risk-based levels of concern Prior to conducting ABS sampling. This allows the project team to ensure that the analytical results will be at or below the risk-based level of concern, which is necessary for evaluating risk and making decisions.

00:42:50.000 --> 00:43:05.000
The appropriate sample volume and flow rate should be determined prior to sampling as well. The EPA grid opening calculator can be used to calculate sample volume and flow rate based on a specified risk-based level of concern.

00:43:05.000 --> 00:43:30.000
Additional information concerning data quality objectives, data management, and establishing levels of concern can be found in the 2021 Framework for Investigating Asbestos Contaminated surplus Sites

00:43:30.000 --> 00:43:42.000
Select perimeter and background sampling locations prior to beginning ABS. Base this decision on grid location and current wind conditions. During the ABS activity event.

00:43:42.000 --> 00:43:48.000
Power sources can include generators. Although there are battery-powered options as well.

00:43:48.000 --> 00:43:54.000
Once locations are determined, set up the sample station, install sample media.

00:43:54.000 --> 00:44:13.000
And calibrate the sample pumps. Log sample media and pump calibration data into field application software.

00:44:13.000 --> 00:44:19.000
Collect personal samples for ABS to properly categorize the levels of airborne asbestos exposures.

00:44:19.000 --> 00:44:26.000
Abs sampling requires a backpack modified to hold a low flow and high flow sample pump.

00:44:26.000 --> 00:44:34.000
With sample cassettes attached. Calibrate each sample pump to a predetermined flow rate. To meet analytical sensitivity requirements.

00:44:34.000 --> 00:44:55.000
Before sampling begins. Secure the sample media to the backpack following calibration. The following image is a typical example of a low flow and high flow sample pump within a backpack.

00:44:55.000 --> 00:45:08.000
Place the apparatus containing the sample pumps and sample media on the participant after they equip PPE.

00:45:08.000 --> 00:45:20.000
Remove caps on sample cassettes. Start the sample pumps and have the participant begin ABS sampling activities.

00:45:20.000 --> 00:45:33.000
Here we see the raking scenario. Each ABS scenario lasts approximately one hour. Rotate participants every 15 to 30 minutes to reduce heat exposure.

00:45:33.000 --> 00:45:41.000
It is important to frequently check sample pumps throughout the sampling period to make sure they are not overloaded and are operating as intended.

00:45:41.000 --> 00:45:51.000
Several site-specific ABS scenarios are available. Here we see a walker with stroller.

00:45:51.000 --> 00:46:13.000
Elite and trailing bicycle. An example of a child playing in dirt scenarios.

00:46:13.000 --> 00:46:39.000
Abs sampling may also be used indoors to characterize risk. Examples of indoor ABS activities include Sweeping, vacuuming, or simulating other activities that may disturb indoor dust.

00:46:39.000 --> 00:46:45.000
Once the ABS scenario is complete, remove the sampling apparatus from the participant.

00:46:45.000 --> 00:47:00.000
Turn off both sample pumps and cap each sample cassette.

00:47:00.000 --> 00:47:12.000
Use a wet wipe to decontaminate equipment and record the final flow rates to allow for calculation of the average flow rate during the sample event.

00:47:12.000 --> 00:47:32.000
Collect samples from the perimeter and background locations. Check flow rates and enter data into field application software.

00:47:32.000 --> 00:47:46.000
Asbestos may be released when soil is disturbed during response activities. Project managers should ensure that dust suppression is used Including spraying with water to minimize dust being generated during site activities.

00:47:46.000 --> 00:48:01.000
Abs can also be used for grid clearance to ensure that contamination does not remain at the site after an action is performed.

00:48:01.000 --> 00:48:09.000
All right. So I'm going to change our view here and call the presentation content back up on the screen.

00:48:09.000 --> 00:48:19.000
And then as I do that, let me click forward here and just call my panelists to come back on camera because we are going to jump into our next Q&A break.

00:48:19.000 --> 00:48:29.000
So I will remind the audience, if you have questions or comments, you can use the Q&A to submit those in privately. We're going to start reading through some of these questions that have come in.

00:48:29.000 --> 00:48:40.000
As the panelists come on camera. So the very first set of questions that I have came in earlier at the beginning of this section, getting into the sampling methodology.

00:48:40.000 --> 00:48:45.000
So this first question wanted to know how exactly does one determine the number of composites?

00:48:45.000 --> 00:48:47.000
When you're sampling.

00:48:47.000 --> 00:49:00.000
Yeah, that's a good question. And we have been doing some research Several of us here on the tr To answer that question, and it looks like the answer is more is better.

00:49:00.000 --> 00:49:14.000
Asbestos in soil is very heterogeneous. You can sample collect samples side by side and get wildly different answers. So the more increments that you use to build your sample.

00:49:14.000 --> 00:49:20.000
The more representative we have found that sample is, and more importantly, the more reproducible it is.

00:49:20.000 --> 00:49:37.000
So if you're looking on that scale of 30 to 100, 100, is where i would land, it's a little more labor intensive. The ITRC guidance calls out a minimum of 30 increments to build your samples, but we've found that

00:49:37.000 --> 00:49:52.000
While that minimum is good for things like metals, it's really not well suited to asbestos. So I would go higher and you know would shoot for close to 100

00:49:52.000 --> 00:50:02.000
Okay. All right. Excellent. And a related question. For soils, how many square feet per sample?

00:50:02.000 --> 00:50:13.000
That's… we don't have a good answer to that. That's going to depend on where you think your asbestos is, how it was released.

00:50:13.000 --> 00:50:24.000
How broadly it might have been spread at your setting. So it's going to be site specific. There's not a good general answer to that question.

00:50:24.000 --> 00:50:34.000
If you're using incremental sampling, as we're discussing. Then you would be using what ITRC calls decision units.

00:50:34.000 --> 00:50:42.000
And those would be based on, again, releases suspected data that you have in hand and other things.

00:50:42.000 --> 00:51:07.000
Generally, you know, we're generally you know we would be collecting those hundred increments across that decision unit. So hopefully that answers your question there but You know, we wouldn't we Typically, we've tried to get away from collecting discrete samples in a grid or otherwise at our sites is just being

00:51:07.000 --> 00:51:11.000
Not representative of the underlying soil.

00:51:11.000 --> 00:51:17.000
Okay.

00:51:17.000 --> 00:51:18.000
Mm-hmm.

00:51:18.000 --> 00:51:29.000
And a decision unit could be as small as, say, a backyard garden or it could be as large as a football field It just depends on on who the receptors might be.

00:51:29.000 --> 00:51:35.000
Uh… other site conditions such as that.

00:51:35.000 --> 00:51:36.000
Okay.

00:51:36.000 --> 00:51:46.000
I'm going to chime in for the lab folks. You want to check with the lab on the total volume of the sample that you're going to submit for analysis, though.

00:51:46.000 --> 00:51:53.000
Make sure that you're not sending them You know, several five gallon buckets worth

00:51:53.000 --> 00:52:12.000
That yeah that is a good… point to the, and I think that came up in one of the slides is If you're collecting incremental samples, 100 increments is going to be close to a five kilogram sample. Jed and his lab might not be too excited to receive

00:52:12.000 --> 00:52:25.000
Five kilograms of contaminated dirt. So you may have to do some soil processing to sub sample Before you send that to the lab. So work closely with your lab on who's going to do that soil processing and where

00:52:25.000 --> 00:52:34.000
And… also incremental sampling. You may collect a certain number of increments in the field when they get to the lab.

00:52:34.000 --> 00:52:42.000
We also will spread that out on a sheet and then redo the increments again to adjust the volume so that that's occurring as well.

00:52:42.000 --> 00:52:48.000
Yeah.

00:52:48.000 --> 00:52:59.000
Right. And that's, again, something that you want to discuss with your lab ahead of time. They may not be super excited to have five kilograms of asbestos contaminated soil spread out.

00:52:59.000 --> 00:53:10.000
And a pan in their lap or they may not be equipped to do that. So you may have to do it in the field Which is something that we have done that sub sampling before sending it off to the lab.

00:53:10.000 --> 00:53:21.000
Okay. And I see some additional questions about ISM. I'm going to take one more and then I'm going to move to another grouping of questions that we have. We may come back to some of these later as time permits.

00:53:21.000 --> 00:53:35.000
But there was an observation simply made that ISM can be expensive and labor intensive. So they're just wondering if you can offer some thoughts if it's really necessary when you're doing soil sampling for asbestos.

00:53:35.000 --> 00:53:41.000
Necessary is a loaded… term, right?

00:53:41.000 --> 00:53:49.000
It can be especially labor intensive when you're in PPE to collect these samples.

00:53:49.000 --> 00:53:59.000
But yeah, I will say that the data that you're going to get from those incremental samples is going to be better than collecting discrete samples.

00:53:59.000 --> 00:54:04.000
So… Depending on your site conditions.

00:54:04.000 --> 00:54:19.000
If you've got percent levels in discrete samples, you probably don't need incremental samples to make site decisions, right? You're going to know that you have elevated concentrations and you can take an action.

00:54:19.000 --> 00:54:22.000
And the framework is intended to be dynamic in that way.

00:54:22.000 --> 00:54:30.000
That if you have a clear cause to go forward. Doing ABS may not be necessary.

00:54:30.000 --> 00:54:37.000
If you see if you've lots of asbestos in soil, that may be all that you need to do to take your action.

00:54:37.000 --> 00:54:46.000
So it's going to be site specific. We just recommend it as a TRW to collect ISM because it gives us better data.

00:54:46.000 --> 00:54:53.000
But it may not be necessary. Air quotes in all cases.

00:54:53.000 --> 00:55:00.000
All right, excellent. I'm going to move on to some questions about dust sampling.

00:55:00.000 --> 00:55:08.000
So this first one is asking, would you assume dust is contaminated if it's observed in the vicinity of damaged insulation, so friable material?

00:55:08.000 --> 00:55:22.000
Or has damaged materials commingled with the dust. Or is there an option to sample out the dust via wipe air bulk sampling?

00:55:22.000 --> 00:55:34.000
I would want analysis on that damaged insulation first. Not just a visual viable insulation next to it but It's a problem.

00:55:34.000 --> 00:55:43.000
You guys can add to it, but it's an additional line of evidence having that dust sample To go along with your bulk sampling.

00:55:43.000 --> 00:55:56.000
And that's usually how we use the dust and wipe samples for additional lines of evidence from something either outside making it inside or outside something inside being friable and causing release inside.

00:55:56.000 --> 00:55:57.000
Okay.

00:55:57.000 --> 00:56:10.000
Yeah, I would just also add, I mean, if there's a especially sensitive receptor, a dust sample could be that extra insurance, like Joey mentioned We have a case study tomorrow.

00:56:10.000 --> 00:56:30.000
Involving a… daycare next to a a building that was damaged that contained asbestos and they did some dust sampling in that daycare to help confirm to the parents and to the teachers that the asbestos to not make its way into the building but

00:56:30.000 --> 00:56:36.000
Like Joey said, the bulk sampling is what you really want to get.

00:56:36.000 --> 00:56:47.000
All right, excellent. And a point of clarification. So one attendee wanted to know why can't soil results be used for risk assessment?

00:56:47.000 --> 00:56:52.000
I think we all have a pretty solid response on this one.

00:56:52.000 --> 00:57:05.000
But I just go that the whole reason you just sat through a 10 minute video on activity-based sampling And why we want to disturb the media, including soil.

00:57:05.000 --> 00:57:22.000
Or sediment or anything that that we could disturb is because it's been demonstrated through pilot studies and sampling experiments, if you want to call them that that 1% of acm or greater.

00:57:22.000 --> 00:57:30.000
Guideline for something being considered asbestos, ACM, asbestos containing material is not protective.

00:57:30.000 --> 00:57:36.000
And it requires a disturbance. And we do that through the scenarios.

00:57:36.000 --> 00:57:53.000
So I think the one, I'm sorry if I'm rambling here but The one case study I remember during this 2004 was the mike cook memo epa memo about this but It showed a bunch of samples collected at about 0.25% soil asbestos and soil.

00:57:53.000 --> 00:57:59.000
And upon disturbing and collecting air samples related to that sample population.

00:57:59.000 --> 00:58:10.000
The levels were losing a risk. I jumbled that all around. So feel free to Give me a little correction there, guys.

00:58:10.000 --> 00:58:19.000
I think you've hit it spot on is that the more complicated answers that the soil doesn't give us air concentrations.

00:58:19.000 --> 00:58:26.000
Our toxicity data for risk assessment is based on inhalation. So we need that concentration in air.

00:58:26.000 --> 00:58:33.000
To do that. We don't have a good method for extrapolating soil concentrations to air.

00:58:33.000 --> 00:58:50.000
And as Joey pointed out. In other kinds of asbestos happening, what seems to be okay getting non-detects or very low concentrations of When disturbed have created air concentrations that present an unacceptable risk.

00:58:50.000 --> 00:58:54.000
So that's really the take home. Of the framework.

00:58:54.000 --> 00:58:59.000
Is that we need to, we're doing all these things to understand the concentration in air.

00:58:59.000 --> 00:59:09.000
That people can be exposed to. And we can use our toxicity information that's based on inhalation In order to do the risk assessment.

00:59:09.000 --> 00:59:17.000
Okay. And could you confirm for another participant about those indoor dust measurements? If you can't use those for risk assessment.

00:59:17.000 --> 00:59:25.000
Then are we sampling just to confirm presence or absence? Of asbestos?

00:59:25.000 --> 00:59:37.000
That's part of it. But again, if we are finding very high concentrations in that dust that can give us an indication that we need to take an action.

00:59:37.000 --> 00:59:54.000
And we wouldn't need to do like indoor ABS there to confirm that so It can serve that purpose to show that there's been a release. It can help us to decide to take an action and waive doing the ABS. So there's several reasons for doing it.

00:59:54.000 --> 01:00:03.000
And also puts together as someone earlier talked about lines of evidence of showing that the lease releases occurred or asbestos from outside has baited inside.

01:00:03.000 --> 01:00:08.000
Those types of things. So I think we have covered that fairly.

01:00:08.000 --> 01:00:21.000
Okay. Can you confirm, does the ABS, the activity-based sampling, include multiple scenarios, raking and lawn mowing?

01:00:21.000 --> 01:00:29.000
It can contain or include multiple scenarios depending on the site-specific.

01:00:29.000 --> 01:00:40.000
Conditions and the conditions and potential receptors that you might be you know that might encounter the site.

01:00:40.000 --> 01:01:05.000
You know, you could have a scenario for mowing a yard uh and uh by a resident and if there's a small garden that gardening might be another exposure scenario that one would need to evaluate.

01:01:05.000 --> 01:01:11.000
So you can have multiple ABS scenarios.

01:01:11.000 --> 01:01:20.000
Depending on site conditions and the receptor population that's involved.

01:01:20.000 --> 01:01:32.000
Okay. A quick question on what we might cover later on in the training. Are we going to look at how to sample materials that are suspected of containing asbestos, like insulation, fireproof drywall?

01:01:32.000 --> 01:01:37.000
And then once that's sampled, what your evaluation criteria would be?

01:01:37.000 --> 01:01:48.000
No. And the reason for that is that there's lots of guidance OSHA guidance, EPA guidance, and then niche apps and AHIRA that cover all that.

01:01:48.000 --> 01:01:58.000
Our primary focus here is on… the asbestos the framework for investigating asbestos contaminated Superfund sites.

01:01:58.000 --> 01:02:03.000
Which kind of goes beyond that that general what I call, you know.

01:02:03.000 --> 01:02:09.000
Everyday asbestos investigation. So no, that's the short answer.

01:02:09.000 --> 01:02:10.000
The kneeship. Is what you're looking for.

01:02:10.000 --> 01:02:11.000
Okay.

01:02:11.000 --> 01:02:15.000
The D-shaps, yes. Yep.

01:02:15.000 --> 01:02:40.000
Okay. I'm going to take another question here. How would you go about using ABS to evaluate the risk of a threatened release, such as a deteriorating building with ACM if it was not safe to enter?

01:02:40.000 --> 01:02:41.000
It's not safe to enter. I don't think we're going to enter it.

01:02:41.000 --> 01:02:42.000
Right.

01:02:42.000 --> 01:02:55.000
Well, you can… Right. Not without levels of protection. So you may want to do some bulk sampling ahead of time to check that. And that's one of the methods we'll talk about coming up.

01:02:55.000 --> 01:03:05.000
All right, excellent. I have several questions that are still coming in, which is fabulous. But I think just in the interest of time, we're going to pause here with the Q&A break.

01:03:05.000 --> 01:03:10.000
We're going to carry on with the presentation. However, we do have another Q&A break scheduled later on in the talk.

01:03:10.000 --> 01:03:16.000
So I'm going to go ahead and let my presenters and panelists turn their cameras off. I want to thank them for their time.

01:03:16.000 --> 01:03:26.000
I'll continue to invite you to peruse through the questions that are coming in. We'll carry on with the presentation. The audience is welcome to continue submitting questions for our speakers.

01:03:26.000 --> 01:03:34.000
And then again, we will have another pause here later on in our session.

01:03:34.000 --> 01:03:42.000
Characterization of potential human exposure to asbestos. Generally involves analytical testing using current methodologies.

01:03:42.000 --> 01:03:48.000
That afford accurate identification of fibrous material present in sample media.

01:03:48.000 --> 01:03:54.000
Accurate and precise quantitative results. Reproducibility among multiple testing laboratories.

01:03:54.000 --> 01:04:02.000
Flexibility, consensus acceptance of the method among asbestos professionals. And cost effectiveness.

01:04:02.000 --> 01:04:10.000
The framework provides recommendations for analyzing asbestos in soil. Settled dust and air.

01:04:10.000 --> 01:04:21.000
Analysis of asbestos in aqueous media is not addressed in the framework Because ingestion of asbestos via drinking water has not historically been considered an important exposure route at surplus sites.

01:04:21.000 --> 01:04:27.000
However, the safe drinking water act includes methods for analyzing asbestos and drinking water.

01:04:27.000 --> 01:04:41.000
If it is determined that asbestos in drinking water may be a complete exposure pathway at a site Remember that error analysis is needed for quantitative risk assessment calculations.

01:04:41.000 --> 01:04:51.000
This slide shows the various instruments that can be used for asbestos analysis.

01:04:51.000 --> 01:04:58.000
For bulk asbestos analysis of soil or ACM, A stereo microscope is used for initial analysis.

01:04:58.000 --> 01:05:07.000
Followed by a polarized light microscope, or PLM. The stereo microscope magnification can range from 6 to 50x.

01:05:07.000 --> 01:05:12.000
The PLM is used to identify asbestos based on optical properties.

01:05:12.000 --> 01:05:19.000
The PLM magnification can range from 100 to 400x.

01:05:19.000 --> 01:05:25.000
The phase contrast microscope, or PCM, is used for analyzing air samples.

01:05:25.000 --> 01:05:30.000
The PCM is used to identify fibers based on morphology only.

01:05:30.000 --> 01:05:40.000
It does not consider chemistry or crystalline structure. The PCM magnification is 400x.

01:05:40.000 --> 01:05:58.000
The scanning electron microscope, or SEM, can be used as an optional method to identify asbestos for either bulk samples or air filters. The SEM electron beam scans the surface of the sample and projects the result as an image of the surface on the screen.

01:05:58.000 --> 01:06:06.000
An SEM can be equipped with energy dispersive X-ray analysis or EDS to determine particle chemistry.

01:06:06.000 --> 01:06:10.000
The SEM has a wide range of magnification.

01:06:10.000 --> 01:06:17.000
From 24 to 300,000x.

01:06:17.000 --> 01:06:27.000
The transmission electron microscope, or TEM, is the recommended method for analyzing air samples and can also be used to analyze bulk samples.

01:06:27.000 --> 01:06:34.000
The TEM transmits an electron beam through the sample. Which projects an image on the screen.

01:06:34.000 --> 01:06:45.000
The TEM can be equipped with EDS. And select area electron diffraction or SAE D to determine chemistry and crystalline structure.

01:06:45.000 --> 01:06:50.000
The TEM can be used at low magnification. Approximately 5,000x.

01:06:50.000 --> 01:06:58.000
Or high magnification, approximately 20,000x.

01:06:58.000 --> 01:07:06.000
The framework presents four analytical methods for asbestos and soil. These methods differ in their preparation steps.

01:07:06.000 --> 01:07:14.000
Method selection is a site-specific decision. The EPA method was developed for bulk building materials.

01:07:14.000 --> 01:07:21.000
Or ACM, but is also used to analyze soil samples. The method includes various analytical techniques.

01:07:21.000 --> 01:07:33.000
But stereomicroscopy and PLM are mandatory. It also includes graphometric matrix reduction, such as ashing to remove cellulose such as leaves.

01:07:33.000 --> 01:07:37.000
Roots and paper. And or dilute acid treatment.

01:07:37.000 --> 01:07:41.000
To remove minerals such as calcite. Dolomite and gypsum.

01:07:41.000 --> 01:07:46.000
That could interfere with analysis. If interfering materials are present.

01:07:46.000 --> 01:07:52.000
Graphometric reduction improves detection of asbestos. And improves data quality.

01:07:52.000 --> 01:08:01.000
Carb435 is a state method developed by the California Air Resources Board For analysis of naturally occurring serpentine aggregate.

01:08:01.000 --> 01:08:06.000
It has been used over the years in a modified form by EPA regions.

01:08:06.000 --> 01:08:12.000
The ASTM method 7521 is specifically for soil analysis.

01:08:12.000 --> 01:08:18.000
It incorporates the gravimetric reduction steps from the EPA method by reference.

01:08:18.000 --> 01:08:25.000
It includes sieving based on particle size. With analysis of separate fractions.

01:08:25.000 --> 01:08:30.000
The optional TEM step in this method may be used for the fine fraction.

01:08:30.000 --> 01:08:40.000
The fluidized bed asbestos segregator will be discussed in more detail in upcoming slides.

01:08:40.000 --> 01:08:45.000
Soil results may guide the placement of air sampling locations for risk assessment.

01:08:45.000 --> 01:08:52.000
Please note that the use of the EPA600 method or other bulk building material methods.

01:08:52.000 --> 01:08:59.000
May exclude structures that would be included in an air sample as cleavage fragments.

01:08:59.000 --> 01:09:05.000
Cleavage fragments are formed by breaking larger mineral particles rather than being fibrous.

01:09:05.000 --> 01:09:13.000
The images on this slide show clear distinctions But many samples may be subject to interpretation.

01:09:13.000 --> 01:09:26.000
Laboratory interpretations of geology may vary. Trw assistance is available If this issue arises in your data.

01:09:26.000 --> 01:09:38.000
The fluidized bed asbestos segregator or FBAS, was developed for EPA to help determine low-level concentrations of asbestos and soil and other matrices.

01:09:38.000 --> 01:09:47.000
Such as vermiculite. It has also been successfully used for the determination of other elongated mineral particles such as Arianite.

01:09:47.000 --> 01:10:00.000
Bulk soil samples are processed in an FBAS using air to illustrate asbestos structures from sample soil and deposit them onto filter for analysis by transmission electron microscopy.

01:10:00.000 --> 01:10:06.000
Or TEM.

01:10:06.000 --> 01:10:19.000
This image shows the FBAS apparatus and its components.

01:10:19.000 --> 01:10:29.000
Other test method 42 is the approved EPA method for sampling Sample preparation, and operation of the fluidized bed asbestos segregator.

01:10:29.000 --> 01:10:41.000
Currently, there is limited availability to FBAS equipment. Epa's Region 10 lab and one commercial lab are the only locations where they are available.

01:10:41.000 --> 01:10:51.000
The FBAS has been incorporated into the framework. Additional research is being conducted to help better interpret data from the FBAS.

01:10:51.000 --> 01:10:56.000
It has been used to analyze samples from multiple sites. Including Davidson asbestos.

01:10:56.000 --> 01:11:06.000
Libby, Northridge Estates. Swift Creek, Frank Foundry, and Dort Food Storage.

01:11:06.000 --> 01:11:16.000
Dust samples analyzed using ASTM method 5755 may be used qualitatively or semi-quantitatively.

01:11:16.000 --> 01:11:21.000
To determine the area of contamination. Or confirm if a release has occurred.

01:11:21.000 --> 01:11:28.000
When analyzing settled dust by TEM, The preparation steps may break asbestos structures.

01:11:28.000 --> 01:11:33.000
Especially chrysotile bundles. Into multiple fibers.

01:11:33.000 --> 01:11:40.000
Also, different counting rules are used, which could potentially lead to higher or lower results than error analysis.

01:11:40.000 --> 01:11:47.000
The small area that is sampled for dust means results may not be representative of a larger area.

01:11:47.000 --> 01:11:56.000
Also, while asbestos and settled dust results may appear high. This does not necessarily indicate high exposure in the breathing zone.

01:11:56.000 --> 01:12:03.000
Trw consultation is recommended for indoor dust scenarios.

01:12:03.000 --> 01:12:10.000
Air samples can be collected from stationary or personal monitors worn during ABS activities.

01:12:10.000 --> 01:12:18.000
Niosh 7400. Is the PCM method that can be used to analyze air samples for screening purposes.

01:12:18.000 --> 01:12:23.000
Pcm cannot distinguish asbestos fibers from non-asbestos fibers.

01:12:23.000 --> 01:12:31.000
So the screening result has limited use. Samples are analyzed at 400x magnification in this method.

01:12:31.000 --> 01:12:37.000
Tem can be used to analyze samples at low and high magnifications.

01:12:37.000 --> 01:12:50.000
There are different methods for direct and indirect TEM analysis. Direct methods retain structures in the same relative position during analysis as they were on the original sample filter.

01:12:50.000 --> 01:13:07.000
Whereas indirect methods involve dispersing the particulate matter from the original sample filter into a liquid and capturing the suspended particulates onto intermediate filters that are then prepared for analysis.

01:13:07.000 --> 01:13:13.000
The next two slides present the asbestos TRWs recommended air analysis approach.

01:13:13.000 --> 01:13:20.000
Tem is preferred to PCM for characterization of exposures to inform decisions at circler sites.

01:13:20.000 --> 01:13:32.000
Samples should be collected on 0.8 micrometer mixed cellulose ester or MCE filters. For most CERCLA air sampling applications to avoid filter overload.

01:13:32.000 --> 01:13:37.000
The photos on this slide show a filter and sampling cassettes with filters.

01:13:37.000 --> 01:13:43.000
Iso method 10312 should be used for direct TEM analysis at a low magnification.

01:13:43.000 --> 01:13:49.000
Of at least 5,000x.

01:13:49.000 --> 01:13:54.000
Pcme counting rules with modifications for structure type should be followed.

01:13:54.000 --> 01:14:03.000
Pcme refers to structure seen in a TEM that are considered equivalent to structures that are visible in a PCM.

01:14:03.000 --> 01:14:13.000
When analyzing asbestos samples. Microscopists refer to a set of rules that dictate which visible structures to be counted or considered asbestos.

01:14:13.000 --> 01:14:22.000
Tem methods require that the microscopist classify each primary fibrous structure into one of the four fundamental categories.

01:14:22.000 --> 01:14:26.000
Fibers, bundles. Clusters and matrices.

01:14:26.000 --> 01:14:33.000
The framework recommends that PCME structures counted include only fibers and bundles.

01:14:33.000 --> 01:14:40.000
With a width range between 0.2 micrometers and 3.0 micrometers.

01:14:40.000 --> 01:14:48.000
A length greater than 5 micrometers and an aspect ratio greater than or equal to 3 to 1.

01:14:48.000 --> 01:14:52.000
The aspect ratio is the ratio of the length to the width of a structure.

01:14:52.000 --> 01:15:01.000
The framework provides additional details about what should be counted by the microscopist.

01:15:01.000 --> 01:15:13.000
Alternate approaches for error analysis include ISO method. 13794 for indirect TEM analysis In ISO method 14966.

01:15:13.000 --> 01:15:22.000
For SEM analysis. The indirect TEM method should only be used when filter overload does not allow for direct analysis.

01:15:22.000 --> 01:15:30.000
The use of indirect analytical results should be considered on a side-by-site basis and may be useful for decision making.

01:15:30.000 --> 01:15:35.000
But direct analytical results are preferred for risk assessment where feasible.

01:15:35.000 --> 01:15:41.000
The SEM method may be used as a supplement to TEM for visualization.

01:15:41.000 --> 01:15:49.000
Sem Analysis will provide more detailed information on surface topography and morphology.

01:15:49.000 --> 01:16:00.000
Sensitivity and detection levels for error analysis by TEM are determined by the volume of air collected and the area of the filter counted by the analyst.

01:16:00.000 --> 01:16:07.000
Sensitivity is defined as the concentration corresponding to the detection of one structure in the analysis.

01:16:07.000 --> 01:16:13.000
The sensitivity for a sample is determined by the volume of air drawn through the sample filter.

01:16:13.000 --> 01:16:20.000
The active area of the filter The number of grid openings on a filter analyzed by a microscopist.

01:16:20.000 --> 01:16:36.000
And the area of each grid opening analyzed. The level of detection, or LOD, is equivalent to a reporting level and expresses the uncertainty around the sensitivity level for non-detects. It is the upper bound of the counting error for zero structures

01:16:36.000 --> 01:16:43.000
And can be calculated as 2.99 times the analytical sensitivity or about three structures.

01:16:43.000 --> 01:16:49.000
The LOD should be at or below the level of concern or LOC.

01:16:49.000 --> 01:16:56.000
There may be several practical constraints that limit the sample volume and the number of grid openings analyzed.

01:16:56.000 --> 01:17:01.000
The volume of air collected is given as the product of pump flow rate and collection time.

01:17:01.000 --> 01:17:11.000
Time for collection of air volume may be limited by the amount of time a sampler is able to maintain an ABS activity and full PPE.

01:17:11.000 --> 01:17:18.000
The maximum sampling time for a personal air sample associated with ABS is usually about two to four hours.

01:17:18.000 --> 01:17:23.000
At some sites, much lower flow rates may be needed to avoid overloading a filter.

01:17:23.000 --> 01:17:37.000
Depending on activity and site conditions. The time and cost of analysis is directly related to the number of grid openings analyzed.

01:17:37.000 --> 01:17:40.000
All right. At this point, we're going to switch over to a short video.

01:17:40.000 --> 01:17:44.000
And then we will have our last Q&A break for the day.

01:17:44.000 --> 01:17:48.000
So I'm going to call up the next video

01:17:48.000 --> 01:18:10.000
Analytical laboratory methods for asbestos. The following video provides a brief overview of analytical methods covered in the 2021 Framework for Investigating Asbestos Contaminated surplus sites. This video will cover typical laboratory methods for analyzing soil and air collected at asbestosites.

01:18:10.000 --> 01:18:24.000
Soil analytical methods for site characterization. Epa 600 method. This method is primarily used to analyze bulk building materials.

01:18:24.000 --> 01:18:36.000
While not a soil method, the EPA 600 method may be necessary on surplus sites which may present situations where soil construction debris and building materials may be present.

01:18:36.000 --> 01:18:44.000
The method includes stereoscopics. Examination followed by a polarized light microscopy techniques.

01:18:44.000 --> 01:18:55.000
The gravimetric reduction preparation method may be included in the EPA 600 method to produce a more accurate estimate for samples in the 1% range.

01:18:55.000 --> 01:19:10.000
Limit for this method is typically 1%. The asbestos mineral type is determined by observations of optical properties such as extinction angle Signs of elongation and dispersion staining.

01:19:10.000 --> 01:19:21.000
California Air Resource Board Method 435. This method was developed to determine asbestos content of serpentine aggregate and is commonly used to detect asbestos.

01:19:21.000 --> 01:19:30.000
Soil. Sample preparation may require a disc mill to achieve desired material size.

01:19:30.000 --> 01:19:37.000
Once required material size is achieved, sample is transferred to a container for stereoscope examination.

01:19:37.000 --> 01:19:46.000
Following stereoscope examination, a slide is prepared for a 400 point count analysis by PLM technique.

01:19:46.000 --> 01:19:58.000
Carb435 method has a detection limit of 0.25%. Astm D7521-16.

01:19:58.000 --> 01:20:07.000
The ASTM method for determination of asbestos in soil is based on sieving of soil rather than grinding homogenation.

01:20:07.000 --> 01:20:18.000
Soil is dried prior to sieve. Once dry, soil is placed in sieve to separate out coarse, medium, and fine fractions.

01:20:18.000 --> 01:20:25.000
The option for a wet sieving procedure is available and can improve detection of asbestos structures.

01:20:25.000 --> 01:20:30.000
The three separate fractions are then weighed and examined with a stereoscope.

01:20:30.000 --> 01:20:38.000
Following visual examination, a slide is prepared from the fine fraction for a 400 point count analysis.

01:20:38.000 --> 01:20:46.000
The slide is then analyzed by PLM analysis. The ASTM method has a detection limit of 0.25%.

01:20:46.000 --> 01:20:57.000
With optional TEM analysis, sensitivity can be achieved to 0.1%. Fluidized bed asbestos segregator.

01:20:57.000 --> 01:21:04.000
This method is designed to quantify mineral fibers present in soil or other solid media.

01:21:04.000 --> 01:21:17.000
This method uses a specialized preparation method followed by TEM analysis. Detection limits of approximately 100 times lower than typical soil methods can be achieved.

01:21:17.000 --> 01:21:26.000
This method has limited laboratory availability and should be discussed prior to field activities.

01:21:26.000 --> 01:21:35.000
Air analytical methods for site characterization. Iso 10312.

01:21:35.000 --> 01:21:42.000
The ISO 10312 method is the recommended method for error analysis under the decision framework.

01:21:42.000 --> 01:21:50.000
The method includes a direct transfer analysis by transmission electron microscopy .

01:21:50.000 --> 01:21:55.000
Sample cassettes are prepared for analysis by placing sample filters on slides.

01:21:55.000 --> 01:22:01.000
Slides are transferred to a plasma asher chamber until the filters are completely ashed.

01:22:01.000 --> 01:22:08.000
Slides are then carbon coated in a vacuum chamber.

01:22:08.000 --> 01:22:18.000
Once sufficient carbon coating is achieved, media is placed on TEM specimen grids.

01:22:18.000 --> 01:22:29.000
Tem specimen grids are then analyzed by TEM method. Analytical sensitivity varies and must be specified by the end user.

01:22:29.000 --> 01:22:38.000
Final results for risk assessment calculations only include structures meeting the PCME requirements for length and width.

01:22:38.000 --> 01:22:47.000
Asbestos is identified by a combination of morphology observed by TEM, Chemistry determined by energy dispersive X-ray analysis.

01:22:47.000 --> 01:22:56.000
And crystal structure determined by select area electron diffraction. Iso 13794.

01:22:56.000 --> 01:23:02.000
It is common for field samples collected for ISO 10312 to become overloaded.

01:23:02.000 --> 01:23:07.000
When a filter becomes overloaded, direct analysis is no longer possible.

01:23:07.000 --> 01:23:23.000
Iso 13794 is an indirect method that can be used to analyze overloaded filters The overloaded filter is removed from the cassette and cut into required sections and placed into a beaker.

01:23:23.000 --> 01:23:34.000
The beaker is placed in a plasma asher until the filter is completely ashed.

01:23:34.000 --> 01:23:51.000
During ashing, the filter apparatus is prepared.

01:23:51.000 --> 01:24:03.000
Once filter is ashed, solution is added and the sample is sonicated.

01:24:03.000 --> 01:24:12.000
Following sonication, the sample is filtered.

01:24:12.000 --> 01:24:25.000
Once liquid is filtered, the filter is removed and placed in a dryer.

01:24:25.000 --> 01:24:41.000
Once sufficiently dry, the filter is prepared for TEM analysis following the ISO 10312 methods previously discussed.

01:24:41.000 --> 01:24:54.000
Niosh 7400 method. Phase contrast microscopy, PCM, is typically used for personal air sampling and perimeter monitoring in occupational environments.

01:24:54.000 --> 01:25:04.000
The NIOSH 7400 method may be a useful screening tool, but it is important to note that the PCM analysis only provides results in fibers.

01:25:04.000 --> 01:25:16.000
And does not determine asbestos concentrations. Sepho cassettes are prepared for analysis by removing one quarter section from the filter to mount on slide for analysis.

01:25:16.000 --> 01:25:28.000
After prepping, the slide is examined by PCM analysis The remaining portions of the filter may be archived for future analysis by TEM methods.

01:25:28.000 --> 01:25:44.000
The PCM method may be conducted on site and may be a quick and cost-effective screening tool at surplus sites. Again, fibers are evaluated by morphology only so asbestos is not differentiated from other fibers.

01:25:44.000 --> 01:25:56.000
Astm D5755. This method is used for determination of asbestos in settled dust.

01:25:56.000 --> 01:26:11.000
Sample is first prepared by rinsing the sample cassette and collecting the rinseate in a beaker.

01:26:11.000 --> 01:26:19.000
The rinse solution is then sonicated.

01:26:19.000 --> 01:26:31.000
During sonication, the filter apparatus is prepared.

01:26:31.000 --> 01:26:43.000
Following sonication, the solution is filtered.

01:26:43.000 --> 01:26:56.000
One solution is removed, the filter is collected and dried.

01:26:56.000 --> 01:27:04.000
After filter is sufficiently dry, the filter is prepared for TEM analysis as previously discussed.

01:27:04.000 --> 01:27:23.000
The steps included in this method are also used to analyze asbestos wipes and asbestos in drinking water.

01:27:23.000 --> 01:27:28.000
Okay, we're now going to move into our final Q&A break for the day.

01:27:28.000 --> 01:27:29.000
So I'm going to invite our

01:27:29.000 --> 01:27:37.000
For further information, please reference the asbestos TRW Technical Resource webpage located here.

01:27:37.000 --> 01:27:44.000
Note that as updated guidance is released by the asbestos TRW, It will be posted to this webpage.

01:27:44.000 --> 01:27:49.000
If you have any asbestos questions or would like an asbestos TRW consultation.

01:27:49.000 --> 01:27:59.000
You can send an email to asbestoshelp at epa.gov or contact your regional TRW representative.

01:27:59.000 --> 01:28:05.000
All right, so I'll invite all of my panelists to come on camera and we'll get ready for our final Q&A segment.

01:28:05.000 --> 01:28:11.000
Again, if you are in the audience, this is your chance to type in questions or comments for our presenters.

01:28:11.000 --> 01:28:22.000
What I'm going to do is start with the questions that came in on this most recent module. We had a few people who commented that they appreciated the video and they are looking forward to when that will be publicly available to replay.

01:28:22.000 --> 01:28:31.000
We do have some questions, though. Regarding some of the analysis work that they saw in the video.

01:28:31.000 --> 01:28:37.000
One of the very first questions. They noticed that the lab tech was not wearing a mask.

01:28:37.000 --> 01:28:46.000
And they just wondered what sort of masks or PPE would normally be used when they were testing for asbestos like that in a lab.

01:28:46.000 --> 01:28:58.000
I can probably take this one. So a lot of the work that they're probably doing is done under HEPA filtration hoods, workstations probably the room too.

01:28:58.000 --> 01:29:16.000
So yeah, they're… Typically, you know, in the lab, you're wearing, you know, gloves, lab coat um But most of the work is where the actual asbestos is being handled is usually in a workstation that's got HEPA filtration.

01:29:16.000 --> 01:29:17.000
Okay, we have a question about Oh, go ahead.

01:29:17.000 --> 01:29:33.000
Yeah, I've seen that too, Jed. Sorry, but I also noticed no gloves and a couple of them too. And I know that's also PPE that sometimes It's just critical and understood that you'll be wearing gloves for some of this prep.

01:29:33.000 --> 01:29:34.000
Excellent.

01:29:34.000 --> 01:29:38.000
And safety glasses.

01:29:38.000 --> 01:29:42.000
Okay, how about the approximate weight of the final sample that is analyzed?

01:29:42.000 --> 01:29:49.000
Someone is wondering how much of the five kilogram sample gets sipped.

01:29:49.000 --> 01:29:50.000
Jed.

01:29:50.000 --> 01:29:58.000
Well, there's two questions there. So the five kilogram sample um Not five kilograms, probably.

01:29:58.000 --> 01:30:05.000
Like I said, when we're doing these incremental samplings, you bring it into the lab.

01:30:05.000 --> 01:30:09.000
You spread it out on a sheet and then you incrementally sample it again.

01:30:09.000 --> 01:30:18.000
You know, 30, 100, however many increments was decided on in the in the planning of the project.

01:30:18.000 --> 01:30:22.000
The amount that actually gets analyzed depends on the method that you're using.

01:30:22.000 --> 01:30:30.000
You know, when you're doing a PLM, it's fractions of a gram um That's spread out on a slide.

01:30:30.000 --> 01:30:52.000
When you're talking about amount of of material that's analyzed under a transmission electron microscope. Boy, I don't even know the weight wouldn't matter. That's more of an area in the area of a TEM grid is only about the size of a head of a pin.

01:30:52.000 --> 01:31:05.000
So it's very small. Not very representative. You know, you probably need to need to consider that when you're trying to interpret the data.

01:31:05.000 --> 01:31:13.000
But I think that That answers both of those questions as best I can.

01:31:13.000 --> 01:31:19.000
Yeah, and there's another question, I think, by the same Ask her.

01:31:19.000 --> 01:31:32.000
The same questioner about the questioner about sample volume and taking increments of the composite how to determine the representatives of the final sample and how that gets analyzed.

01:31:32.000 --> 01:31:39.000
You know, one of the things that we can do is take take replicate samples of that sample.

01:31:39.000 --> 01:31:57.000
But incremental sampling is all about maintaining that representativeness five kilograms sounds like a lot of dirt, but when you're looking over a half acre, an acre of soil, that's a pretty small amount And you want to make sure that what you're aiming to do is make sure that that sample is representative

01:31:57.000 --> 01:32:18.000
Of your decision unit, whatever goes under Jed's um onto his slides for microscopy should be representative of that larger sample so there's things that we can do to be systematic and rigorous in how we pick the very small amount that actually gets analyzed.

01:32:18.000 --> 01:32:36.000
But this gets to some of the complexity of addressing soil asbestos and soil in the first place. And it is very complicated But one of the things that you can do to see if that sample that fraction of a gram is representative of the larger samples

01:32:36.000 --> 01:32:46.000
Take replicates of that sample. Incrementally subsample it several times and see if you're getting kind of concordant answers.

01:32:46.000 --> 01:33:02.000
And that would all be covered under the planning, the quality assurance project plan Your frequency of duplicates and replicates You know, that's just part of the QA program.

01:33:02.000 --> 01:33:12.000
Speaking of replicates, do you have a suggestion on the number of replicates that is recommended for each decision unit for ISM?

01:33:12.000 --> 01:33:18.000
Sure. Yeah. What standard is doing three triplicates.

01:33:18.000 --> 01:33:29.000
In one study, we… Did five because we wanted to see if it mattered yeah if we got… more samples, would that give us more power in our statistics?

01:33:29.000 --> 01:33:44.000
We were collecting 100 increment samples in a quarter acres. So we had 500 holes in the ground that might have been more than we needed. I think we replicants is what we typically do.

01:33:44.000 --> 01:33:52.000
Okay. Does EPA require analysis of vermiculite insulation to confirm the presence of asbestos?

01:33:52.000 --> 01:33:57.000
If so, what analytical method is used?

01:33:57.000 --> 01:34:02.000
I know that PLM. Which is for bulk sample analysis would be recommended.

01:34:02.000 --> 01:34:12.000
But getting to the first part of the question. I have seen advice that assume all vermiculite insulation.

01:34:12.000 --> 01:34:19.000
May contain asbestos. But the reality is you won't know without lab analysis.

01:34:19.000 --> 01:34:28.000
So I don't know. I don't think we actually require vermiculate insulation be be sampled.

01:34:28.000 --> 01:34:32.000
Undergo PLM. But that's just one of those. Go ahead, David.

01:34:32.000 --> 01:34:33.000
Good night.

01:34:33.000 --> 01:34:49.000
Oh. There is a program Sponsored by… W.R. Grace to analyze vermiculite from home insulation.

01:34:49.000 --> 01:35:07.000
And that's the zonolite attic insulation trust. And… if you suspect that you have vermiculite in your attic insulation You can contact them.

01:35:07.000 --> 01:35:19.000
They will send you a container and a shipping container. And you can take a sample of that material, put it in the container and send it to them.

01:35:19.000 --> 01:35:26.000
And they will determine whether or not that vermiculite came from from Libya or not.

01:35:26.000 --> 01:35:34.000
And if it did come from Libby, there is some financial help.

01:35:34.000 --> 01:35:47.000
That is offered through the trust. That allows you to pay for part of the removal of the material from your attic.

01:35:47.000 --> 01:35:57.000
And I just wanted to add, there is actually an EPA research method for sampling and analysis of fibrous amphibole and vermiculite attic insulation.

01:35:57.000 --> 01:36:02.000
Epa 600 slash dash 04 slash 004.

01:36:02.000 --> 01:36:28.000
And I'll write that one down in the chat. That is a method that can be used. It's similar to the certainly the steps in the analysis are similar to the EPA 600 method. The bulk uh building material method, but it's got some interesting information on the unique optical properties of the

01:36:28.000 --> 01:36:32.000
Amphibole found in vermiculite.

01:36:32.000 --> 01:36:38.000
Okay. Speaking of vermiculate, someone is asking if it's used in potting soils.

01:36:38.000 --> 01:36:46.000
And they then go on to say, well, wouldn't it be reasonable to suspect that any vermiculite might have asbestos?

01:36:46.000 --> 01:36:53.000
Yes, that's true. And one of the things that we used to pack our samples in was vermiculite way back in the day.

01:36:53.000 --> 01:37:03.000
So that was also a requirement that we could not ship asbestos samples in vermiculite. So yes, that is a potential issue.

01:37:03.000 --> 01:37:12.000
Okay. We have a question about that. Pesky building that is unsafe to go into for sampling purposes.

01:37:12.000 --> 01:37:18.000
If asbestos contamination is suspected inside a building or other area that is unsafe to enter.

01:37:18.000 --> 01:37:29.000
Might remote control vehicles or drones be used for sampling?

01:37:29.000 --> 01:37:39.000
They might. I'm not aware of that ever having occurred.

01:37:39.000 --> 01:37:44.000
It's not something that we've done. It's not to say that it couldn't be.

01:37:44.000 --> 01:37:53.000
Yeah, so UAS for drones, obviously were used quite a bit for wildfire response and uh We're approaching unsafe buildings.

01:37:53.000 --> 01:38:08.000
Mainly just for visual and video reconnaissance to send back to someone that could sit at a comfy desktop and say, oh, that looks like there's some translate there or Or maybe identify some of the hazards before the samples were collected or

01:38:08.000 --> 01:38:13.000
Safety precautions were taken.

01:38:13.000 --> 01:38:29.000
Okay. A question about soils. Why would you suspect asbestos in the soils in the first place? Is this to look for naturally occurring asbestos sites where there was an old building that was demolished? We have an attendee who joined a little bit late. So just to recap if somebody missed this in the beginning.

01:38:29.000 --> 01:38:33.000
Welcome to the Superfund program. All of the above.

01:38:33.000 --> 01:38:36.000
All of the above.

01:38:36.000 --> 01:38:43.000
Mining would be disturbance of naturally occurring buildings that have been knocked over.

01:38:43.000 --> 01:38:55.000
We've had several sites where unscrupulous people have come in to strip the insulation off of pipes to to steal the pipes for recycling.

01:38:55.000 --> 01:39:06.000
Which has resulted in widespread damage and spreading the the uh the asbestos all over the surrounding soils.

01:39:06.000 --> 01:39:15.000
So there's all kinds of ways that that they end up in the soil and it becomes a super fund.

01:39:15.000 --> 01:39:22.000
Issue.

01:39:22.000 --> 01:39:23.000
Yeah.

01:39:23.000 --> 01:39:33.000
Yeah, a big one from Tim's region are botched cleanups, botched B shaft cleanups where someone's trying to undertake it and they only get so far, either run out of money or interest or or resources to do it.

01:39:33.000 --> 01:39:36.000
Stuff is just scattered, right? Scattered in an old building or the property around it or stored out back, whatever it might be.

01:39:36.000 --> 01:39:56.000
Yeah. Yeah, we had a case where we had a case a… criminals they went to jail recruited people at the corner liquor store to come in and remove the asbestos and They weren't trained.

01:39:56.000 --> 01:40:07.000
So they were breaking ocean you know osha violations knee shops violations, just all sorts of laws and regulations and they went to jail.

01:40:07.000 --> 01:40:14.000
But yeah, when it becomes a super fund issue, things have gone wrong.

01:40:14.000 --> 01:40:26.000
Okay. A question about personal exposure monitoring. Should results from that work And when it's collected, should it be collected to provide a NEA during sampling?

01:40:26.000 --> 01:40:33.000
And then be used as a line of evidence that asbestos is or is not a concern at a site.

01:40:33.000 --> 01:40:39.000
We've had a site where a negative exposure assessment, those of you who don't know what NEA is.

01:40:39.000 --> 01:40:47.000
That's an OSHA thing. It can be it has some similarities to ABS.

01:40:47.000 --> 01:40:53.000
You know, it's workers. In protective equipment.

01:40:53.000 --> 01:41:10.000
With personal air monitoring. We've had a site where we've had a site NEA was used just to downgrade the workers stuff but it's it's not a An NEA is not a not an EPA sampling protocol.

01:41:10.000 --> 01:41:32.000
There, we knew that there was asbestos present we had data And, you know, to show that it needed to be removed it was just an occupational health thing and what the workers were. So no, we didn't use it as a line of evidence in that case. Has anybody else encountered

01:41:32.000 --> 01:41:41.000
Nea at your sites?

01:41:41.000 --> 01:41:47.000
Doesn't sound like it. Yeah, so it's not… It's not something that we use.

01:41:47.000 --> 01:42:09.000
Okay. All right, I'm going to go to a question. If you have buried non-fryable material in soil What parameters would you analyze for soil to confirm the presence of asbestos?

01:42:09.000 --> 01:42:15.000
Well, I guess we would be sampling or asbestos, if I'm understanding the question.

01:42:15.000 --> 01:42:22.000
Correctly we would be using our standard, you know, one of the analytical methods that we've talked about.

01:42:22.000 --> 01:42:28.000
Today. To analyze that soil and determine if that's present.

01:42:28.000 --> 01:42:29.000
Yeah.

01:42:29.000 --> 01:42:38.000
Obviously, if it's buried, we can't do anything like ABS. Because it's buried. So we would um you know to collect the samples and analyze them for asbestos.

01:42:38.000 --> 01:42:59.000
To see if they're present. We might look in the soils that we're collecting to see if there's any visible ACM, asbestos containing materials that might lead us to indicate that the subsurface is even contaminated.

01:42:59.000 --> 01:43:00.000
Yes.

01:43:00.000 --> 01:43:06.000
This is kind of like the Northridge Estates or the Mountain Home Air Force Base where the non-fryable stuff got buried. But over time It's going to resurface.

01:43:06.000 --> 01:43:07.000
Yeah.

01:43:07.000 --> 01:43:24.000
It will, you know, through erosion and frost heaving and different things like that, the active moisture on the on the material will eventually affect the stability of it and it'll start to release fibers And then you may find it in the soil.

01:43:24.000 --> 01:43:33.000
But yeah, you're kind of looking at two different things there the the uh the bulk material and then the soil.

01:43:33.000 --> 01:43:36.000
And eventually the one is going to wind up in the other.

01:43:36.000 --> 01:43:53.000
Okay. And speaking of that. Is there any evidence of upward migration of asbestos fibers through soil? They specifically asked about a scenario with ACM capped in place and weather factors like freezing and thawing.

01:43:53.000 --> 01:44:06.000
Yes. And that… example that Chad just talked about in North Ridge Estates is This may be the classic you know they would clean up the surface soil And think they were done in a year later.

01:44:06.000 --> 01:44:10.000
There's more asbestos visible at the surface. So yes, that is a common That is something that can happen.

01:44:10.000 --> 01:44:17.000
Yeah. Yeah, it's called biopperturbation.

01:44:17.000 --> 01:44:26.000
And just, I think a related question, is there data on temporal effects of soil borne air asbestos concentrations?

01:44:26.000 --> 01:44:42.000
With regard to ACM weathering. They wonder, will ABS results be similar now compared to 100 years in the future after weathering?

01:44:42.000 --> 01:44:44.000
We haven't done the 100-year test yet, but yet

01:44:44.000 --> 01:44:53.000
Good question. Yeah, I… we would suspect that over 100 years that those fibers would break up.

01:44:53.000 --> 01:44:57.000
And be probably result in higher.

01:44:57.000 --> 01:45:03.000
Concentrations over time. But yeah, I'm not aware of any studies that have looked at it.

01:45:03.000 --> 01:45:04.000
Temporally.

01:45:04.000 --> 01:45:12.000
Can we repeat the study that showed upward migration? What was the name of the site?

01:45:12.000 --> 01:45:13.000
Northridge Estates.

01:45:13.000 --> 01:45:14.000
Northridge estate? Yeah.

01:45:14.000 --> 01:45:31.000
Northridge Estates, okay. All right. Okay. Let's talk a little bit about wipe and soil samples. This one came in earlier in the session today and one of the participants wondered, should wipe and soil samples be used to assess risk to potential future receptors?

01:45:31.000 --> 01:45:44.000
Whereas air is better for current receptors. They note that wipe and soil analytical results could inform about what has the potential to be mobilized to the air conditions, which are different than current.

01:45:44.000 --> 01:45:45.000
Yeah.

01:45:45.000 --> 01:45:52.000
The only metric that we have for assessing risk is via the inhalation pathway.

01:45:52.000 --> 01:45:59.000
Those are the only toxicity factors that we have are for inhalation exposures only.

01:45:59.000 --> 01:46:04.000
So we are limited to assessing risk.

01:46:04.000 --> 01:46:10.000
To the air pathway.

01:46:10.000 --> 01:46:11.000
Okay.

01:46:11.000 --> 01:46:26.000
Yeah. And again, you would… maybe collect those soil and dust samples to to better understand where the releases have occurred, where you might want to collect air data where you might want to do ABS and things like that.

01:46:26.000 --> 01:46:34.000
It definitely plays a role in your investigation, but the risk assessment is always going to be on the air.

01:46:34.000 --> 01:46:35.000
It helps target, target where you want to do your ABS.

01:46:35.000 --> 01:46:38.000
Okay.

01:46:38.000 --> 01:46:40.000
Yeah.

01:46:40.000 --> 01:46:49.000
Okay. A question about a site that has a remedy that's been implemented and your site is currently in O&M operation and maintenance.

01:46:49.000 --> 01:46:55.000
They wonder how often would you recommend ambient air sampling in ABS?

01:46:55.000 --> 01:47:00.000
I'll speak on this one a little bit. The site I'm currently working on.

01:47:00.000 --> 01:47:05.000
It's part of the rod requires that this be done in addition to soil sampling.

01:47:05.000 --> 01:47:22.000
For other parameters as well. So we've done it three years in a row, but it varies. It all depends if you're If it's dictated in the rod or If you do some visual inspections, I know there's been multiple sites that have had

01:47:22.000 --> 01:47:30.000
Boring animals come up and bring things to the surface. So there's something you may want to look at as you go forward.

01:47:30.000 --> 01:47:38.000
So yeah, as far as recommendation It's just part of your regular O&M inspector cap. If you see something, you might have to do something.

01:47:38.000 --> 01:47:40.000
Okay.

01:47:40.000 --> 01:47:56.000
The other situation that we've have in our region The remedy was conducted under our removal program by time critical removal action by our emergency response group.

01:47:56.000 --> 01:48:16.000
And it was a fill material was from an asbestos plant was used in residential yards And we sampled as many yards as we could. And there was an understanding that there may continue to be asbestos present. So part of the long-term operations and maintenance of the city

01:48:16.000 --> 01:48:27.000
In the state have taken on. Is working with the utilities and landowners If they encounter ACMC, it triggers.

01:48:27.000 --> 01:48:32.000
Some actions that that the property owner will need to take.

01:48:32.000 --> 01:48:38.000
Or the utilities will need to implement to keep their workers safe, keep the residents safe.

01:48:38.000 --> 01:48:44.000
It's going to be site specific and depend on It depends on the remedy.

01:48:44.000 --> 01:48:58.000
If there's anything left, you know, many remedies We'll hopefully have addressed all the material present but you know in in the case cases where you're unsure there's some uncertainty, you can put some measures in place.

01:48:58.000 --> 01:49:06.000
Okay, I know we are coming close to our scheduled end time, so we'll take one or two more questions with the time that we have remaining.

01:49:06.000 --> 01:49:10.000
And then I do have some additional reminders before we close things out today.

01:49:10.000 --> 01:49:18.000
This next one. Gets into just thoughts or considerations for state regulators.

01:49:18.000 --> 01:49:38.000
So they wonder if you have some ideas of some obstacles that our state regulators who are accepting risk-based ABS sampling for site characterization and closure might encounter.

01:49:38.000 --> 01:49:44.000
That's hard to answer from our position as feds.

01:49:44.000 --> 01:49:52.000
I think it would… may maybe just depend on

01:49:52.000 --> 01:50:12.000
The state's asbestos program, they will have a delegated program they have asbestos folks, you know, they have hazardous waste folks who were dealing with circular like projects. I think it's just going to depend on the state and the personnel that they have.

01:50:12.000 --> 01:50:20.000
But, you know. We on the TRW are always available to assist in any way that we can.

01:50:20.000 --> 01:50:34.000
So if a state folks that are on If you're wanting to pursue this or you've somebody hands you the data and you need some assistance interpreting it, you can feel free to reach out.

01:50:34.000 --> 01:50:39.000
To us anytime via the The link here.

01:50:39.000 --> 01:50:40.000
Okay.

01:50:40.000 --> 01:51:01.000
And I would only add cost considerations. Some of the ABS samples, depending on the sensitivity required. If you can't collect enough volume on your sample media you may have to count additional grids in order to meet that sensitivity and that's where you can run into cost overruns in your original budget.

01:51:01.000 --> 01:51:06.000
Okay, excellent. Now, I did see a number of questions that came into the queue earlier.

01:51:06.000 --> 01:51:23.000
I'm sorry, there's a lot of positive feedback that just came in some of the attendees have been very engaged today, so they appreciated your time and expertise but A number of people have asked risk related questions. And I know that the webinar is going to carry on tomorrow and in

01:51:23.000 --> 01:51:31.000
Part two, we'll talk a bit about risk. But I wanted to offer perhaps a sneak peek motivation. This is an ecological risk question.

01:51:31.000 --> 01:51:39.000
They just wonder if there's evidence of bioaccumulation or biomagnification of ACM in wildlife.

01:51:39.000 --> 01:51:58.000
I might be able to take that one. So in general, the exposure and the effects of asbestos through inhalation, it's a long-term chronic kind of thing and kind of thing again in speaking in generalities, many of the wildlife don't live long enough

01:51:58.000 --> 01:52:08.000
To show the impacts. It's still an inhalation aspect. So they'd have to be in an area where they could breathe it in.

01:52:08.000 --> 01:52:14.000
We generally don't see a lot with ecological risk in asbestos.

01:52:14.000 --> 01:52:15.000
All right, excellent.

01:52:15.000 --> 01:52:23.000
We do, however, know. That in the case of the Libya asbestos Superfund site.

01:52:23.000 --> 01:52:33.000
That… mineral fibers have been detected in fish tissue and in animal tissues.

01:52:33.000 --> 01:52:44.000
That. Where either the fish or the uh the land-based animal has come in contact with either soil or water.

01:52:44.000 --> 01:52:50.000
So we do know that mineral fibers do get into the tissues.

01:52:50.000 --> 01:53:00.000
Of ecological receptors. We don't have any ecological benchmarks to assess asbestos.

01:53:00.000 --> 01:53:07.000
Toxicity and… ecological receptors.

01:53:07.000 --> 01:53:17.000
But we do know that we do know that mineral fibers have been detected in ecological critters.

01:53:17.000 --> 01:53:27.000
All right. Well, with that and just a minute or two remaining on our time, I'm going to go ahead and close out This portion of part one in our final Q&A break.

01:53:27.000 --> 01:53:35.000
And I want to thank our panelists for joining us today, as well as the over 200 live attendees who were here for today's broadcast.

01:53:35.000 --> 01:53:44.000
And I want to make sure that everyone comes back tomorrow for part two, the final part in this series on the framework for investigating asbestos contaminated circle sites.

01:53:44.000 --> 01:53:53.000
For those of you that found this to be a very engaging and eye-opening seminar, the fun continues tomorrow at 1 p.m. Eastern, where we'll be joined by the same panel of experts.

01:53:53.000 --> 01:53:59.000
With a few additional guests. So I encourage you to make sure you have it on your calendar. You'll participate.

01:53:59.000 --> 01:54:03.000
Connect following the exact same instructions that you used for today.

01:54:03.000 --> 01:54:10.000
And if you have a colleague that you think could benefit from it, registration is still open. They are certainly welcome to sign up and join us for part two.

01:54:10.000 --> 01:54:16.000
Again, which will take place on Cluwen. I'm going to walk through just a few quick final reminders today before we close things out.

01:54:16.000 --> 01:54:24.000
So hopefully you all are familiar with the cleanup information network or cluwen.org and are visiting that as a hazardous waste site cleanup or characterization professional.

01:54:24.000 --> 01:54:31.000
Make sure you are subscribed for our free monthly newsletter, Tech Direct. I send that out on the first of each month and we'll highlight free sessions like today's.

01:54:31.000 --> 01:54:46.000
Webinar. And I'll also remind everybody, if you joined us late, there is a unique seminar homepage. You can see it in red on the slide. It's also available through the QR code. That website will remain active from today forward. It is where we have posted the presentation materials, copies of the framework, links to the videos.

01:54:46.000 --> 01:54:57.000
I will be adding in some of the additional references that we included in the meeting chat, such as the link to the Northridge Estates and the additional research paper that was put in there on the vermiculate analysis method.

01:54:57.000 --> 01:55:09.000
So make sure you bookmark that and reference it. You can also share that link with others. And for those of you looking for participation or certificates for joining us today, you can get one of those by filling out our short online feedback form.

01:55:09.000 --> 01:55:23.000
So if you go to the seminar homepage, scroll down to this section on feedback and fill it out. Once you submit it, making sure you check the box at the bottom of the form certifying you were here for the entire live delivery. As soon as you submit it, you'll then have access to download or print out a participation certificate.

01:55:23.000 --> 01:55:31.000
If you hosted a viewing party and I saw that there were five of you out there who did, which meant a group of you collected together in a room to watch this together.

01:55:31.000 --> 01:55:39.000
Whoever signed up, simply send the people who joined you the link to that homepage. They can each fill out their own feedback form and get their own certificate, even though they didn't register on their own.

01:55:39.000 --> 01:55:48.000
And please know, I read each and every one of those forms and I really do count on your feedback to help improve and continue to offer free technical sessions.

01:55:48.000 --> 01:55:59.000
Like today's webinar. Today's session was recorded and will be automatically archived on the Clutin webinar. All registrants will get an email from me as soon as part one is available. It usually takes me about a week or so to post that archive.

01:55:59.000 --> 01:56:09.000
And if you happen to be one of the lucky people that have made it this far and are watching the recording from today, you too can share feedback and get your own certificate based on replaying the archived webinar.

01:56:09.000 --> 01:56:18.000
Right about now in the recording above my head in the upper right, there will be a button that will take you to that same feedback form. You can fill it out and get your own certificate based on the replay.

01:56:18.000 --> 01:56:24.000
With that, again, I want to thank our panelists, our organizers, and those of you who joined us for today's live broadcast.

01:56:24.000 --> 01:56:27.000
And I hope to see you all back here tomorrow at 1 p.m. For part two.

01:56:27.000 --> 01:56:30.000
This is the formal conclusion for today's live broadcast. Thank you so very much for joining us.

01:56:30.000 --> 01:56:37.000
Yeah.
