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OVERCOMING THE EFFECTS OF HETEROGENEITIES IN DNAPL SOURCE ZONE REMEDIATIONMeinardus, Hans W., Intera, Inc., Austin, TX. SERDP/ESTCP Partners in Environmental Technology Technical Symposium & Workshop, 2-4 December 2003, Washington, DC. Technical Session Abstracts, p 54, 2003
Surfactant-enhanced aquifer remediation (SEAR) offers proven techniques for
overcoming the effects of geological heterogeneities, such as low permeability
silty sands in an otherwise coarse sand aquifer. First used for enhanced oil
recovery (EOR), these techniques involve changing the viscosity of the fluids
in situ to raise pore pressures and divert injected surfactant solutions away
from the high permeability zones. The viscosity of the DNAPL determines the
choice of viscosifier: polymers for high-viscosity DNAPLs such as coal tar and
creosote, and surfactant foams for low-viscosity DNAPLs such as chlorinated
solvents. George Hirasaki of Rice University, who developed the concept as an
EOR tool while with Shell Oil, pioneered the use of surfactant-foam flooding
with INTERA at Hill AFB, UT. The DNAPL source zone at Hill originally
contained 50,000 gallons of waste chlorinated degreasing solvent from aircraft
maintenance operations. This DNAPL is approximately 75% TCE. Contrary to
conventional wisdom, this DNAPL wets the sand and gravel aquifer. Because the
aquifer at Hill is highly heterogeneous, surfactant flooding could result in
removal of DNAPL preferentially from the coarse zones without removing the
DNAPL from the finer-grained zones just above the stratigraphic trap formed by
the underlying clays. Injecting air into the surfactant stream at periodic
intervals so that viscous foam forms in the permeable zones of the aquifer
already cleaned of DNAPL can prevent this preferential removal, because the
foam is of sufficient viscosity to divert subsequently injected surfactant
into lower permeability sands at the base of the aquifer. During 2001-2002,
Hirasaki and INTERA undertook the removal of the remaining residual DNAPL from
the Hill AFB aquifer using large-scale foam floods that appear to have removed
all remaining DNAPL.
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